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15 - States of Matter
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15.1 Gases

15.1.1 : PV = nRT ... P=(pressure in atm) V=(volume in cm3) n=(number of atoms in mols) R=(82.05 cm3 atm K-1 mol-1 -- in data book) T=(temperature in K)

15.1.2 : The above equation can be rearranged as P1V1=P2V2 or V1/T1=V2/T2 if temp or pressure are assumed to be constant. Avogadro's law -- equal volumes of gas contain equal numbers of particles (at 273K, 1 atm -> 22.4 dm3 mol-1 -- in data book)

15.1.3 : Dalton's law of partial pressures -> the partial pressure of a gas is the pressure the gas would exert if the gas were alone in its container. ie if there are Gases A, B and C filling a dm3, b dm3 and c dm3 respectively then the partial pressure of a = (a)/(a+b+c) x total pressure.

15.1.4 : Pp = (number of molecules in the gas)/(total number of molecules) x total pressure ... apply this relationship...

Nb -- Apparently, though it's never been in the syllabus, there have been questions on Van Der Wall's equation, which is an extension of PV=nRT for non-ideal gas situations...it is (P+an2/V2)(V-nb)=nRT Where a and b are constants for a given gas...which I assume will be given if necessary.

Other Notes in this Category

  1. 01 - Stoichiometry
  2. 02 - Atomic Theory
  3. 03 - Periodicity
  4. 04 - Bonding
  5. 05 - States of Matter
  6. 06 - Energetics
  7. 07 - Kinetics
  8. 08 - Equilibrium
  9. 09 - Acids and Bases
  10. 10 - Oxidation and Reduction
  11. 11 - Organic Chemistry
  12. 12 - Atomic Theory
  13. 13 - Periodicity
  14. 14 - Bonding
  15. 15 - States of Matter
  16. 16 - Energetics
  17. 17 - Kinetics
  18. 18 - Equilibrium
  19. 19 - Acids and Bases
  20. 20 - Oxidation and Reduction
  21. 21 - Organic Chemistry

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